Bile Acids and Steroids. XV. Thiosteroids. (4). Ring-opening Reaction of 11β, 12β-Episulfide with Acetic Anhydride and p-Toluenesulfonic Acid.
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چکیده
منابع مشابه
Synthesis and optimization ring opening of monoepoxide linoleic acid using p-toluenesulfonic acid
Biolubricant base oils, 9,12-hydroxy-10,13-oleioxy-12-octadecanoic acid (HYOOA) was synthesized based on the esterification reaction of Monoepoxide linoleic acid 9(12)-10(13)-monoepoxy 12(9)-octadecanoic acid (MEOA) with oleic acid (OA) and catalyzed by p-Toluenesulfonic acid. The optimum conditions for the experiment using D-optimal design to obtain high yield% of 84.61, conversion% of 83.54 a...
متن کاملBile Acids and Steroids
In several mammalian species, i.e. rabbit, dog and man, deoxycholic acid is one of the main bile acids in the bile (1). In recent years evidence has accumulated that deoxycholic acid is formed from cholic acid during the enterohepatic circulation by the action of intestinal microorganisms. By the use of 24-@-labeled cholic acid this conversion has been demonstrated in rabbit and in man (2,3). B...
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A new procedure for analyses for tryptophan in proteins and glycoproteins is described. The method utilizes ptoluenesulfonic acid as the catalyst for hydrolysis and the amino acid analyzer for the quantitative estimation of tryptophan. The hydrolysis of proteins is carried out in 3 N p-toluenesulfonic acid containing 0.2 % 3-(Z-aminoethyl)indole in evacuated sealed tubes at 110” for 22, 48, and...
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برهمکنش dnaتیموس گاوی طبیعی (ct-dna) با اتیلن دی آمین تترااستات (edta)در بافرtris-hcl با 8/7 ph ( دراین ph،edta به نمک دی سدیم تبدیل می شود) وسسامول در بافر tris-hcl با4/7 ph مورد بررسی قرار گرفته است. edta و سسامول استفاده فراوانی در تکنولوژی غذایی و صنعت شیمیایی دارند. مدل اتصال dna مربوط بهedta بوسیله اسپکتروفتومتری جذب، دورنگ نمایی حلقوی(cd)، ویسکومتری وژل الکتروفورز بررسی شده است. طیفuv ...
15 صفحه اولSteroids Derived from Bile Acids
Derivatives of bile acids with substituents in Ring C have been described in the preceding papers of this series (l-6). It is the purpose of this paper to assign the probable stereochemical configurations for these compounds. As desoxycholic acid (I)l is a convenient reference compound, it will first be necessary to discuss briefly the spatial arrangement of certain portions of this bile acid. ...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1960
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.8.668